Druh výsledku: Článek v odborném periodiku (Article in a professional journal)
ISSN: 1022-5528
Vydáno/uděleno: 2010
Link: Link URL
DOI: 10.1007/s11244-009-9421-z

Popis

The catalysts were tested in a flow reactor at reaction temperatures 300 and 320 _C, hydrogen pressures 2–11 MPa and space velocities 1–4 h-1 using refined rapeseed oil as a feedstock. Incorporation of Al into the framework of MCM-41 led to an increase of both conversion of triglycerides and selectivity to hydrocarbons, namely n-heptadecane and n-octadecane. However, the conversion of triglycerides was lower than that achieved over alumina supported CoMo. Moreover, the rather high selectivity to oxygenated products, as compared with alumina supports, has made possible a detailed description of the reaction intermediates and their dependence on the reaction conditions.